玻璃材料高速抛光用固着磨料磨具试验研究

目的实现玻璃材料的高效高质量低成本抛光。方法选择不同添加剂作为辅料制作固着磨料抛光磨具,阐明制作工艺流程、添加剂辅料配方及比例、固着磨料磨具对材料硬度、剪切强度等性能的影响。以工件材料去除率、表面质量以及磨耗比等作为评价指标分析不同添加剂辅料对加工效果的影响,并通过等效系数优化方法确定添加剂辅料的最优配方。结果碳化硅与钼酸铵可增加磨具的硬度和剪切强度,磨具中加入适量氧化铝可有效提高工件表面质量。结论固着磨料抛光磨具的添加剂辅料最优配方为:10.6%(质量分数)4000#Al2O3和2%(质量分数)10000#SiC。     

OER properties of Ni–Co–CeO2/Ni composite electrode prepared by magnetically induced jet electrodeposition

Hydrogen production from water electrolysis with catalysts is a simple, effective, and environmentally friendly way. However, the slow kinetics of the oxygen evolution reaction (OER) directly affects the catalytic efficiency of water electrolysis during hydrogen production. While the high cost of noble metal catalysts limits their engineering applications. Therefore, there is an urgent need to develop an economical and abundant catalyst with efficient OER performance to replace noble metal catalysts to reduce costs. In this work, we propose a method for the preparation of composite catalytic electrodes by magnetically induced jet electrodeposition. Ni–Co–CeO₂/Ni composite electrodes with a unique micro-nano structure and a large specific surface area were rapidly obtained through magnetically induced adsorption of nano-mixed particles. It was found that the Ni–Co–CeO₂/Ni composite electrode deposited by magnetically induced electrodeposition exhibited a lower overpotential of 301 mV@10 mA/cm² when the nano-mixed particle concentration was 2 g/L, and the corresponding Tafel slope was as low as 43.72 mV/dec. The key parameters of overpotential and Tafel slope reach or even outperform the best noble metal electrode in the industry, indicating that the Ni–Co–CeO₂/Ni composite electrode had excellent OER catalytic performance. The study demonstrates that magnetically induced jet electrodeposition provides a new method for the preparation of catalytic electrodes, which has important applications in the electrolysis of water for hydrogen production.